Cacodyle

Chambers's Encyclopaedia, Volume 2: Beaugency to Cataract, p. 611

Cacodyle, or KAKODYLE, is an organic substance containing carbon, hydrogen, and arsenic, ((\text{CH}_3)_2\text{As})_2. The oxide of cacodyle, ((\text{CH}_3)_2\text{As})_2\text{O}, otherwise known as Cadet's fuming liquor or alkarsine, has the remarkable property of taking fire spontaneously when exposed to the air, and evolving abundant and exceedingly poisonous fumes of arsenic.

Source scan(s): p. 0624