Case-hardening is the process of converting the surface of certain kinds of malleable-iron goods into steel, thereby making them harder, less liable to rust, and capable of taking on a better polish. Fire-irons, gun-locks, keys, and other articles of limited size, are very commonly so treated, but the process is sometimes applied to large objects, such as iron railway-bars. The articles are first formed, and heated to redness with powdered charcoal or cast-iron, the malleable-iron taking carbon from either of these to form a skin of steel upon it; the heated objects are then cooled in cold water, or in oil when they are of a delicate nature. Yellow prussiate of potash or parings of leather have also been a good deal used for coating iron articles with steel by heating them together. Some chemists consider that in this case nitrogen combines with the iron and effects the hardening. The coating of steel is very thin, seldom exceeding th of an inch. A Swedish ironmaster has found that a very excellent case-hardening is obtained by treating iron or steel objects with a mixture of animal matter, such as rasped leather or horn, and arsenious acid dissolved in hydrochloric acid, and heating as usual.
Case-hardening
Chambers's Encyclopaedia, Volume 2: Beaugency to Cataract, p. 805
Source scan(s): p. 0822