Pyrophorus (from the Gr. pyr, 'fire,' and pherō, 'I bear') is a term applied to any substances which take fire from the rapidity with which they are oxidised. If iron, cobalt, or nickel be reduced by hydrogen from its oxide at a low red heat, it is obtained in a state of such extreme division as to become incandescent by the oxidising action of the atmosphere; and the tendency to rapid oxidation is much increased by the interposition of some infusible matter, as a little alumina or magnesia, between the particles of the oxide. This is probably due to the cohesion of the minute particles of the reduced metal being thus mechanically prevented, and the access of air to the surface of each particle being thus facilitated. If tartrate of lead be heated in a tube till the organic portion becomes charred, the metallic lead is reduced to a state of extreme subdivision, and usually takes fire when poured into the air. If finely-powdered sulphate of potash be mixed with half its weight of lamp-black, and heated in a covered crucible, the sulphate is reduced to sulphide of potassium, which remains in a finely-divided state, mixed with the excess of carbon, and takes fire spontaneously in the air from the rapid absorption of oxygen. These are amongst the best examples of pyrophori.
Pyrophorus
Chambers's Encyclopaedia, Volume 8: Peasant to Eoumelia, p. 508
Source scan(s): p. 0517